Chemical elements
  Barium
    Isotopes
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      Barium Hydride
      Barium Subfluoride
      Barium Fluoride
      Acid Barium Fluoride
      Barium Subchloride
      Barium Chloride
      Barium Bromide
      Barium Perbromides
      Barium Iodide
      Barium Periodides
      Barium Mixed Halides
      Barium Mixed Perhalides
      Barium Oxychloride
      Barium Hypochlorite
      Barium Chlorite
      Barium Chlorate
      Barium Perchlorate
      Barium Oxybromide
      Barium Hypobromite
      Barium Bromate
      Barium Perbromate
      Barium Oxyiodide
      Barium Iodate
      Barium Periodate
      Barium Manganites
      Barium Manganate
      Barium Permanganate
      Barium Suboxide
      Barium Oxide
      Barium Hydroxide
      Barium Peroxide
      Barium Peroxyhydrate
      Barium Tetroxide
      Barium Sulphide
      Barium Hydrosulphide
      Barium Polysulphides
      Barium Hydroxyhydrosulphide
      Barium Oxysulphides
      Barium Sulphite
      Barium Thiosulphate
      Barium Dithionate
      Barium Trithionate
      Barium Tetrathionate
      Barium Pentathionate
      Barium Sulphate
      Acid Barium Sulphates
      Barium Pyrosulphate
      Barium Persulphate
      Barium Selenide
      Barium Selenite
      Barium Selenate
      Acid Barium Selenate
      Barium Telluride
      Barium Tellurite
      Barium Tellurate
      Barium Chromite
      Barium Chromate
      Barium Dichromate
      Barium Potassium Trichromate
      Barium Chlorochromate
      Barium Perchromate
      Barium Molybdate
      Barium Permolybdate
      Barium Tungstate
      Barium Uranate
      Barium Diuranate
      Barium Peruranate
      Barium Nitride
      Barium Azide
      Barium Hexammoniate
      Barium Ammonium
      Barium Amide
      Baramide
      Barium Amidosulphonate
      Barium Imide
      Barium Imidosulphonate
      Barium Hyponitrite
      Barium Nitroxysulphite
      Barium Nitrososulphate
      Barium Nitrohydroxylaminate
      Barium Nitrite
      Barium Nitrate
      Barium Phosphide
      Barium Dihydrohypophosphite
      Barium Hydrophosphite
      Barium Hypophosphate
      Barium Orthophosphates
      Barium Pyrophosphate
      Barium Metaphosphate
      Basic Barium Phosphates
      Barium Thiophosphites
      Barium Thiophosphates
      Barium Selenophosphates
      Barium Azophosphates
      Barium Phosphimates
      Barium Arsenide
      Barium Orthoarsenite
      Barium Pyroarsenite
      Barium Orthoarsenates
      Barium Pyroarsenate
      Barium Thioarsenites
      Barium Thioarsenates
      Barium Sodium Selenoxyarsenate
      Barium Metantimonate
      Barium Thioantimonites
      Barium Chloroantimonite
      Barium Orthothioantimonate
      Barium Hypovanadate
      Barium Vanadates
      Barium Metapervanadate
      Barium Niobate
      Barium Tantalate
      Barium Pertantalate
      Barium Carbide
      Barium Carbonyl
      Barium Formate
      Barium Acetate
      Barium Oxalate
      Barium Carbonate
      Barium Thiocarbonate
      Barium Percarbonate
      Barium Cyanide
      Barium Cyanamide
      Barium Cyanate
      Barium Cyanurate
      Barium Thiocyanate
      Barium Selenocyanate
      Barium Silicide
      Barium Silicates
      Barium Fluosilicate
      Barium Stannate
      Barium Orthoplumbate
      Barium Titanate
      Barium Peroxide Pertitanate
      Barium Pertitanate
      Barium Fluoroxytitanate
      Barium Zirconate
      Barium Boride
      Barium Borates
      Barium Fluorborate
      Barium Perborate
      Barium Aluminates
      Barium Ferrite
      Barium Ferrate
      Barium Gobaltite
      Barium Dinickelite
      Barium Platinate
    Detection of Barrium
    PDB 1djh-3iqp
    PDB 3iqr-4e7y

Barium Chlorate, Ba(ClO3)2






Barium Chlorate, Ba(ClO3)2, is formed by the neutralisation of barium hydroxide or carbonate with chloric acid. It may also be precipitated by the action of ammonium chlorate, or aluminium chlorate, on barium carbonate, preferably in boiling alcohol. By the action of chlorine at 80° C. on barium hydroxide solution, or on barium carbonate suspended in water, chlorate mixed with chloride is obtained. The latter can, for the most part, be removed by recrystallisation.

From solution the monohydrate separates out in colourless, monoclinic crystals. The chlorates of the alkaline earths exhibit crystallo- luminescence on crystallising out. The density is 3.179, and the specific heat 0.157. The salt loses its water of crystallisation at 180° C., and slowly decomposes at 300°-310° C., with the formation of perchlorate and chloride and the loss of oxygen. The rate of decomposition increases with rise of temperature, and the reaction continues until about 10 per cent, of oxygen has been lost.

When mixed with a reducing agent, barium chlorate readily explodes. It reacts with iodine, forming iodic and chloric acids and barium iodide. With sulphurous acid at 60° C. barium sulphate and chlorine monoxide are obtained. Sulphuric acid decomposes it with the production of light. The heat of solution of the anhydrous salt is -6.7 Cal. The heat of solution of the monohydrate is -11.24 Cal., and, therefore, the heat of hydration is 4.54 Cal.

The following values have been found for the solubility: -

Temperature, °C-2.749±0.004 cryohydric point010203040506070809099.1105° boiling-point
Grams anhydrous salt per 100 grams solution15.2816.921.2325.2629.4333.1636.6940.0543.0445.9048.4751.1752.67


The vapour pressures and refractive indices of barium chlorate solutions have been determined.

The salt is only slightly soluble in alcohol.

Barium chlorate is used in pyrotechnics for the production of green fire.


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